Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Ammonia → Tatb
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Ammonia | HCID 222 | — |
| 반응물 | Pentanitroaniline | HCID 11023554 | — |
| 용매 | Benzene | HCID 241 | — |
| 용매 | Dichloromethane | HCID 6344 | — |
| 생성물 | Tatb | HCID 18286 | — |
반응 단계
According to this invention, the 4-nitro group or trinitrotoluene (TNT) is selectively reduced by H2S in p-dioxane to produce 4-amino-2,6-dinitrotoluene. This latter compound is then nitrated with HNO3 in H2SO4 to produce pentanitroaniline. Finally the pentanitroaniline is reacted with NH3 in benzene, methylene chloride or another suitable solvent to produce a quantitative yield of TATB. The method of this invention is easily carried out and all reactants are inexpensive.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04248798 |
| 출처 데이터셋 | uspto-grants-1981_02 |
| ORD ID | ord-c283ec2468c44de395a48e3784755499 |
| 출처 메모 | uspto-grants-1981_02 |