Chlorobenzene → 2,8-Dimethyl-4-methylenenonane

HRID 1414139

반응식

HRID 1414139 반응식
[CH3:1][CH:2]([CH3:6])[CH2:3][CH:4]=[CH2:5].[Cl-].[Cl-].[CH2:9]([Al+2])C.Cl[C:13]1[CH:18]=[CH:17][CH:16]=[CH:15]C=1>[Cl-].[Cl-].C1([Ti+2]C2C=CC=C2)C=CC=C1.N12CCN(CC1)CC2>[CH2:3]([C:4]([CH2:13][CH2:18][CH2:17][CH:16]([CH3:15])[CH3:9])=[CH2:5])[CH:2]([CH3:6])[CH3:1]

참가 물질

6

반응물 3

HCID 7964ChlorobenzeneHCID 127244-Methyl-1-penteneHCID 16686341Ethyl aluminium dichloride

생성물 1

HCID 5446682,8-Dimethyl-4-methylenenonane

시약·촉매·용매 2

HCID 9237Dabco촉매HCID 178420582HCID 178420582, 화합물촉매

실험 절차

To a 30 ml glass bottle, under an argon atmosphere, were added 7.2 milligrams (0.029 millimol) of di(cyclopentadienyl)titanium dichloride, 8 mg (0.072 millimol) of 1,4-diazabicyclo(2.2.2)octane, 5 ml (40.0 millimol) of 4-methyl-1-pentene, 7 ml of chlorobenzene, and 0.045 ml (0.44 millimol) of ethylaluminum dichloride. After a two hour reaction at 25° C., there had been formed 1.08 millimol of 2-isobutyl-6-methyl-1-heptene.

후처리

  1. customAfter a two hour reaction at 25° C.

출처 및 근거

ORD 기록
ord-4c693585f82049dcac967349712c78cb
출처 데이터셋
uspto-grants-1981_02
특허 번호
US04252987

연결된 노트

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