홈MCP워크벤치Skills
홈워크벤치알림마이페이지
llms.txt · MCP 가이드개인정보처리방침 · 이용약관 · 지원v1.8.0
  1. 홈
  2. /반응

1-Aminoanthraquinone → Anthrimide

HRID 1414217
노트
인쇄 미리보기

반응식

HRID 1414217 반응식
C1(N2C[C:11]3[C:13]4[C:22]([C:23](Cl)=[CH:24][C:10]=3N=C2)=C[C:20]2[C:15](=[CH:16][CH:17]=[CH:18][CH:19]=2)[CH:14]=4)C=CC=CC=1.[NH2:26][C:27]1[C:40]2[C:39](=[O:41])[C:38]3[C:33](=[CH:34][CH:35]=[CH:36][CH:37]=3)[C:32](=[O:42])[C:31]=2[CH:30]=[CH:29][CH:28]=1.[C:43](=[O:46])(O)[O-].[Na+].[N+](C1C=CC=CC=1)([O-])=[O:49]>[Cu]>[CH:35]1[CH:34]=[C:33]2[C:32]([C:31]3[CH:30]=[CH:29][CH:28]=[C:27]([NH:26][C:11]4[C:13]5[C:14]([C:15]6[C:20]([C:43](=[O:46])[C:22]=5[CH:23]=[CH:24][CH:10]=4)=[CH:19][CH:18]=[CH:17][CH:16]=6)=[O:49])[C:40]=3[C:39](=[O:41])[C:38]2=[CH:37][CH:36]=1)=[O:42]
참가 물질실험 절차후처리출처 및 근거반응 노트

참가 물질

6

반응물 4

HCID 67101-AminoanthraquinoneHCID 7416NitrobenzeneHCID 516892Sodium BicarbonateHCID 867343472-Phenyl-6-chloroanthrapyrimidine

생성물 1

HCID 6700Anthrimide

시약·촉매·용매 1

HCID 23978Copper촉매

실험 절차

A mixture of 34.3 parts of 2-phenyl-6-chloroanthrapyrimidine, 24 parts of 1-aminoanthraquinone, 15 parts of sodium bicarbonate, 0.5 part of copper powder and 0.5 part of copper-I chloride in 500 parts of nitrobenzene is stirred under reflux for 4 hours. After cooling, the crystalline dyestuff which has precipitated is filtered off, washed successively with a little nitrobenzene, then with warm alcohol and finally with hot water, and dried in vacuo at 80° - 90°C. 46 parts are obtained of the anthrimide of the formula ##SPC8##

후처리

  1. temperatureunder reflux for 4 hours
  2. temperatureAfter cooling
  3. customthe crystalline dyestuff which has precipitated
  4. filtrationis filtered off
  5. washwashed successively with a little nitrobenzene
  6. dry with materialwith warm alcohol and finally with hot water, and dried in vacuo at 80° - 90°C

출처 및 근거

ORD 기록
ord-42969ec707c24f23a5573a9b79d7017e
출처 데이터셋
uspto-grants-1977_01
DOI
10.6084/m9.figshare.5104873.v1
특허 번호
US04001170

반응 노트

불러오는 중…

이 페이지에서참가 물질실험 절차후처리출처 및 근거반응 노트