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Water → 2-Phenyl-6-phenylmercaptoanthrapyrimidine

HRID 1414219
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인쇄 미리보기

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HRID 1414219 반응식
[OH-].[K+].O.[C:4]1([SH:10])[CH:9]=[CH:8][CH:7]=[CH:6][CH:5]=1.[C:11]1([N:17]2[CH2:22][C:21]3[C:23]4[C:32]([C:33](Cl)=[CH:34][C:20]=3[N:19]=[CH:18]2)=[CH:31][C:30]2[C:25](=[CH:26][CH:27]=[CH:28][CH:29]=2)[CH:24]=4)[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=1>CN(C)C=O>[C:11]1([N:17]2[CH2:22][C:21]3[C:23]4[C:32]([C:33]([S:10][C:4]5[CH:9]=[CH:8][CH:7]=[CH:6][CH:5]=5)=[CH:34][C:20]=3[N:19]=[CH:18]2)=[CH:31][C:30]2[C:25](=[CH:26][CH:27]=[CH:28][CH:29]=2)[CH:24]=4)[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=1
참가 물질실험 절차후처리출처 및 근거반응 노트

참가 물질

6

반응물 4

HCID 962WaterHCID 7969ThiophenolHCID 14797Potassium HydroxideHCID 867343472-Phenyl-6-chloroanthrapyrimidine

생성물 1

HCID 867343462-Phenyl-6-phenylmercaptoanthrapyrimidine

시약·촉매·용매 1

HCID 6228Dimethylformamide용매

실험 절차

A solution of 40 parts of potassium hydroxide in 60 parts of water is added to a solution of 66 parts of thiophenol in 1,000 parts of dimethylformamide and 171 parts of 2-phenyl-6-chloroanthrapyrimidine are then introduced. The mixture is stirred for 16 hours at room temperature and afterwards for a further hour at 50°-60°C. After cooling to room temperature, the colorant, which has precipitated in orange crystalline platelets, is filtered off, washed with DMF and alcohol and dried at 80°-90°C in vacuo. 194 parts (93.2% of theory) are obtained of 2-phenyl-6-phenylmercaptoanthrapyrimidine, which dyes polyester in bulk in fast, yellow shades.

후처리

  1. additionare then introduced
  2. temperatureAfter cooling to room temperature
  3. customthe colorant, which has precipitated in orange crystalline platelets
  4. filtrationis filtered off
  5. washwashed with DMF and alcohol
  6. customdried at 80°-90°C in vacuo

출처 및 근거

ORD 기록
ord-cc8097537b9346929bb23b7cc91c28e3
출처 데이터셋
uspto-grants-1977_01
DOI
10.6084/m9.figshare.5104873.v1
특허 번호
US04001170

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