1,1,3,3-Tetramethylguanidine → HCID 57036510, 화합물

HRID 1415101노트

반응식

HRID 1415101 반응식
Cl([O-])(=O)(=O)=O.[CH3:6][C:7]1[N+:12]2[C:13]3[C:18]([C:19]([CH3:21])([CH3:20])[C:11]=2[CH:10]=[CH:9][CH:8]=1)=[CH:17][CH:16]=[CH:15][CH:14]=3.N([CH:29]=[C:30]1[C:35](=[O:36])[N:34]([CH2:37][CH3:38])[C:33](=[S:39])[N:32]([CH2:40][CH3:41])[C:31]1=[O:42])C1C=CC=CC=1.CN(C)C(=N)N(C)C>C(#N)C>[CH2:37]([N:34]1[C:35](=[O:36])[C:30](=[CH:29][CH:6]=[C:7]2[N:12]3[C:13]4[C:18]([C:19]([CH3:21])([CH3:20])[C:11]3=[CH:10][CH:9]=[CH:8]2)=[CH:17][CH:16]=[CH:15][CH:14]=4)[C:31](=[O:42])[N:32]([CH2:40][CH3:41])[C:33]1=[S:39])[CH3:38]

참가 물질

5

반응물 3

HCID 664601,1,3,3-TetramethylguanidineHCID 12374357HCID 12374357, 화합물HCID 178462959HCID 178462959, 화합물

생성물 1

HCID 57036510HCID 57036510, 화합물

시약·촉매·용매 1

HCID 6342Acetonitrile용매

실험 절차

6,10,10-Trimethylpyrido[1,2-a]indolium perchlorate (0.62 g.) and 5-anilinomethylene-1,3-diethyl-2-thiobarbituric acid (0.6 g.) are dissolved in acetonitrile. Tetramethylguanidine (0.23 g.) is added and the reaction mixture is stirred at room temperature overnight. The precipitated dye is filtered off and recrystallized from acetonitrile. The λmax of the product in a mixture of pyridine and methyl alcohol is 513 nm.

후처리

  1. filtrationThe precipitated dye is filtered off
  2. customrecrystallized from acetonitrile
  3. additionThe λmax of the product in a mixture of pyridine and methyl alcohol

출처 및 근거

ORD 기록
ord-51bfed45694d4ab889a9449f148d2acc
출처 데이터셋
uspto-grants-1977_01
특허 번호
US04003750

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