Acetone → 6-Methylhepta-3,5-dien-2-one

HRID 1415462

반응식

HRID 1415462 반응식
[CH3:1][C:2]([CH3:6])=[CH:3][CH:4]=O.[CH3:7][C:8]([CH3:10])=[O:9]>[O-2].[Zn+2]>[CH3:1][C:2](=[CH:3][CH:4]=[CH:7][C:8](=[O:9])[CH3:10])[CH3:6]

참가 물질

4

반응물 2

HCID 180AcetoneHCID 610203-Methyl-2-butenal

생성물 1

HCID 279716-Methylhepta-3,5-dien-2-one수율 93%

시약·촉매·용매 1

HCID 3007857Zinc Oxide촉매

반응 조건

온도
180 °C

실험 절차

A mixture of 50 parts of 3,3-dimethylacrolein, 100 parts of acetone and 12 parts of zinc oxide is heated for 3 hours at 180° C and a pressure of 45 atmosphere in a vibrated autoclave. The reactor is then cooled and the mixture is fractionally distilled. 52.5 parts of 2-methyl-2,4-heptadien-6-one is obtained in a yield of 93% of theory based on 3,3-dimethylacrolein at a conversion 76% of theory and with a boiling point of 92° C at 15 mm Hg.

후처리

  1. temperatureThe reactor is then cooled
  2. distillationthe mixture is fractionally distilled

출처 및 근거

ORD 기록
ord-9bade372e3a34e03b1da0aa1d20b767b
출처 데이터셋
uspto-grants-1977_01
특허 번호
US04005147

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