Methane → rac-(3aR,7aS)-hexahydro-4,7-ethanoindene-1,3-dione

HRID 1415574

반응식

HRID 1415574 반응식
[CH:1]12[CH2:11][CH2:10][CH:7]([CH:8]=[CH:9]1)[CH:6]1[CH:2]2[C:3](=[O:13])[CH2:4][C:5]1=[O:12].C>>[CH:7]12[CH2:8][CH2:9][CH:1]([CH2:11][CH2:10]1)[CH:2]1[CH:6]2[C:5](=[O:12])[CH2:4][C:3]1=[O:13]

참가 물질

3

반응물 2

HCID 297MethaneHCID 53663301rac-(3aR,4S,7R,7aS)-3a,4,7,7a-tetrahydro-4,7-ethanoindene-1,3-dione

생성물 1

HCID 54026023rac-(3aR,7aS)-hexahydro-4,7-ethanoindene-1,3-dione

실험 절차

Reduction of tricyclo [5,2,2,02,6 ] undec-8-ene-3,5-dione over 10% palladinised charcoal as described in example 2a gave the title compound; m.p. (MeOH) 254°- 5° C.

출처 및 근거

ORD 기록
ord-2edacc029e0342868c30fca7eff82fe9
출처 데이터셋
uspto-grants-1977_01
특허 번호
US04005219

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