Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Acetate → 1-Chloro-5-decene
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Acetate | HCID 175 | — |
| 반응물 | 1-Hexene | HCID 11597 | — |
| 반응물 | Dec-5-enyl acetate | HCID 38027 | — |
| 반응물 | 6-Chloro-1-hexene | HCID 70233 | — |
| 반응물 | E-5-Decen-1-ol | HCID 92458 | — |
| 생성물 | 1-Chloro-5-decene | HCID 3085570 | — |
반응 단계
Peach Twig Borer (PTB) pheromone is a mixture of 5-decenyl acetate and 5-decenol of approximately 85:15 molar ratio of the acetate to the alcohol. The synthesis of PTB pheromoneqcouples 1-chloro-5-hexene and 1-hexene to yield 1-chloro-5-decene. 1-chloro-5-decene is converted to 5-decenyl acetate, isomerized and a portion of the acetate is hydrolyzed to the corresponding alcohol to yield PTB pheromone. The overall scheme using the catalyst of Example 1 is shown below, followed by details of the synthesis. ##STR1##
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05916983 |
| 출처 데이터셋 | uspto-grants-1999_06 |
| ORD ID | ord-0baa56873c364be08c9a01cfe82c6012 |
| 출처 메모 | uspto-grants-1999_06 |