[CH3:1][S:2][C:3]1[S:4][C:5]([CH:8]=O)=[CH:6][CH:7]=1.[F:10][C:11]([F:25])([F:24])[C:12]1[CH:17]=[CH:16][C:15]([S:18]([CH2:21][C:22]#[N:23])(=[O:20])=[O:19])=[CH:14][CH:13]=1>>[CH3:1][S:2][C:3]1[S:4][C:5](/[CH:8]=[C:21](/[S:18]([C:15]2[CH:14]=[CH:13][C:12]([C:11]([F:25])([F:10])[F:24])=[CH:17][CH:16]=2)(=[O:20])=[O:19])\[C:22]#[N:23])=[CH:6][CH:7]=1Reaction of 2-methylmercaptothiophen-5-carboxaldehyde and 4-trifluoromethylphenylsulfonylacetonitrile as in Example 1 gave (E)-3-(2-methylmercaptothien-5-yl)-2-[4-(trifluoromethyl)phenylsulfonyl]acrylonitrile
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