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Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
HRID 1433868생성일: 2026년 10월 26일

4-Bromo-3-nitrobenzotrifluoride → 7-Methoxy-3-(2-nitro-4-trifluoromethylphenyl)-1,2-dihydronaphthalene

https://huagongshe.com/reaction/1433868

반응식

참여 물질

역할이름HCID투입량
반응물4-Bromo-3-nitrobenzotrifluorideHCID 520706—
반응물6-Methoxy-3,4-dihydronaphthalen-2-yl trifluoromethanesulfonateHCID 15330256—
반응물Tributyl(2-nitro-4-trifluoromethylphenyl)tinHCID 23087363—
생성물7-Methoxy-3-(2-nitro-4-trifluoromethylphenyl)-1,2-dihydronaphthaleneHCID 23087467—

반응 단계

Synthesized from 1-bromo-2-nitro-4-trifluoromethylbenzene according to an analogous synthetic method to Preparation Example 76, tributyl(2-nitro-4-trifluoromethylphenyl)tin (7.4 g) and 6-methoxy-3,4-dihydronaphthalen-2-yl trifluoromethanesulfonate (2.2 g) were used according to an analogous synthetic method to Preparation Example 77 to provide 7-methoxy-3-(2-nitro-4-trifluoromethylphenyl)-1,2-dihydronaphthalene (1.5 g). The total amount of this compound was used according to an analogous synthetic method to Example 30 to provide the title compound (1.0 g).

출처 및 근거

DOI10.6084/m9.figshare.5104873.v1
특허 번호US07612114B2
출처 데이터셋uspto-grants-2009_11
ORD IDord-d00daee45e914c9cbcda05ad34a62def
출처 메모uspto-grants-2009_11