2-Methoxy-8,9-dihydro-5H-benzo[7]annulen-6(7H)-one → HCID 66626968, 화합물

HRID 1433891

반응식

HRID 1433891 반응식
[CH3:1][O:2][C:3]1[CH:4]=[CH:5][C:6]2[CH2:12][C:11](=O)[CH2:10][CH2:9][CH2:8][C:7]=2[CH:14]=1.FC(F)(F)S(OC1CCCC2C=C(OC)C=CC=2C=1)(=O)=O.C([Sn](CCCC)(CCCC)[C:41]1[CH:46]=[CH:45][C:44]([O:47][CH3:48])=[CH:43][C:42]=1[N+:49]([O-:51])=[O:50])CCC>>[CH3:1][O:2][C:3]1[CH:4]=[CH:5][C:6]2[CH:12]=[C:11]([C:41]3[CH:46]=[CH:45][C:44]([O:47][CH3:48])=[CH:43][C:42]=3[N+:49]([O-:51])=[O:50])[CH2:10][CH2:9][CH2:8][C:7]=2[CH:14]=1

참가 물질

4

반응물 3

HCID 123691772-Methoxy-8,9-dihydro-5H-benzo[7]annulen-6(7H)-oneHCID 23087474Tributyl(4-methoxy-2-nitrophenyl)tinHCID 86605238HCID 86605238, 화합물

생성물 1

HCID 66626968HCID 66626968, 화합물

실험 절차

Synthesized from 2-methoxy-5,7,8,9-tetrahydrobenzocyclohepten-6-one according to an analogous synthetic method to Preparation Example 82, 2-methoxy-8,9-dihydro-7H-benzocyclohepten-6-yl trifluoromethanesulfonate (3.0 g) and tributyl(4-methoxy-2-nitrophenyl)tin (10.8 g) were used according to an analogous synthetic method to Preparation Example 77 to provide the title compound (2.8 g).

후처리

  1. customwere used according to an analogous synthetic method to Preparation Example 77

출처 및 근거

ORD 기록
ord-da2c626018c74dd2bd3ba753b6f2cbb0
출처 데이터셋
uspto-grants-2009_11
특허 번호
US07612114B2

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