Cyclohexanone, 2-propyl- → Methyl 3-(1-methyl-2-oxocyclohexyl)propanoate

HRID 1438917

반응식

HRID 1438917 반응식
CC1CCCCC1=O.C(C1CCCCC1=O)C.C(C1CCCCC1=O)CC.[CH3:28][O:29][C:30](=[O:42])[CH2:31][CH2:32][C:33]1([CH2:40]C)[CH2:38][CH2:37][CH2:36][CH2:35][C:34]1=[O:39].COC(=O)CCC1(CCC)CCCCC1=O>>[CH3:28][O:29][C:30](=[O:42])[CH2:31][CH2:32][C:33]1([CH3:40])[CH2:38][CH2:37][CH2:36][CH2:35][C:34]1=[O:39]

참가 물질

6

반응물 5

HCID 7199Cyclohexanone, 2-propyl-HCID 114192-MethylcyclohexanoneHCID 204742-EthylcyclohexanoneHCID 122918881-Ethyl-2-oxocyclohexanepropionic acid methyl esterHCID 227572861-Propyl-2-oxocyclohexanepropionic methyl ester

생성물 1

HCID 574325Methyl 3-(1-methyl-2-oxocyclohexyl)propanoate

실험 절차

in the same manner but replacing 2-methylcyclohexanone with an equivalent amount of 2-ethylcyclohexanone or 2-propylcyclohexanone, 1-ethyl-2-oxocyclohexanepropionic acid methyl ester, bp 117° - 120° C/0.4mm, and 1-propyl-2-oxocyclohexanepropionic methyl ester, νmaxCHCl3 1735, 1700cm-1, are obtained, respectively.

후처리

  1. customνmaxCHCl3 1735, 1700cm-1, are obtained

출처 및 근거

ORD 기록
ord-024b0687b64941429e696cf79681d3c6
출처 데이터셋
uspto-grants-1977_11
특허 번호
US04057559

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