Hexafluoroacetone → 2,2-Bis(trifluoromethyl)-4-hydroxymethyl-1,3-dioxolane

HRID 1439522노트

반응식

HRID 1439522 반응식
[F:1][C:2]([F:10])([F:9])[C:3]([C:5]([F:8])([F:7])[F:6])=[O:4].[OH:11][CH2:12][CH:13]1[CH2:17]OC(=O)[O:14]1>>[F:1][C:2]([F:10])([F:9])[C:3]1([C:5]([F:8])([F:7])[F:6])[O:14][CH:13]([CH2:12][OH:11])[CH2:17][O:4]1

참가 물질

3

반응물 2

HCID 12695HexafluoroacetoneHCID 97944Glycerol carbonate

생성물 1

HCID 219971032,2-Bis(trifluoromethyl)-4-hydroxymethyl-1,3-dioxolane수율 66%

실험 절차

8.5 grams of this hydroxyethyl hemiketal of hexafluoroacetone is then reacted with 3 grams of glycerol carbonate at 115°-141° C. for 103 hours. The yield is 66% 2,2-bis(trifluoromethyl)-4-hydroxymethyl-1,3-dioxolane.

출처 및 근거

ORD 기록
ord-591059ed401c48fd9a67644ca48ed125
출처 데이터셋
uspto-grants-1977_11
특허 번호
US04060532

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