3-(Tert-butoxy)-1-iodohexane → HCID 178443582, 화합물

HRID 1439667노트

반응식

HRID 1439667 반응식
C(OC(CCCCC)CCI)(C)(C)C.C(OC(CCC)CCI)(C)(C)C.[C:27]([O:31][CH:32]([C:37]#[C:38][CH2:39][CH2:40][CH3:41])[CH2:33][CH2:34][Mg:35][I:36])([CH3:30])([CH3:29])[CH3:28].C(OC(C#CCCC)CCI)(C)(C)C>>[C:27]([O:31][CH:32]([CH2:37][CH2:38][CH2:39][CH2:40][CH3:41])[CH2:33][CH2:34][Mg:35][I:36])([CH3:30])([CH3:29])[CH3:28].[C:27]([O:31][CH:32]([CH2:37][CH2:38][CH3:39])[CH2:33][CH2:34][Mg:35][I:36])([CH3:30])([CH3:29])[CH3:28]

참가 물질

6

반응물 4

HCID 204656183-(Tert-butoxy)-1-iodohexaneHCID 204656323-tert-Butoxy-1-iodooctaneHCID 204657473-t-Butoxy-1-iodo-4-octyneHCID 178443581HCID 178443581, 화합물

생성물 2

HCID 178443582HCID 178443582, 화합물HCID 178444612HCID 178444612, 화합물

실험 절차

Treatment of the cyclopentenones designated in the table below with the designated Grignard reagents by the procedure of Example 493 is productive of the alkyl 9-oxo-15-t-butoxy-8 ξ-prostanoates and prostenoates of the table. 3-t-Butoxyoctylmagnesium iodide was prepared from 3-t-butoxy-1-iodooctane (Example 492); 3-t-butoxyhexyl magnesium iodide was prepared from 3-t-butoxy-1-iodohexane (Example 502), 3-t-butoxy-4-octynyl magnesium iodide was prepared from 3-t-butoxy-1-iodo-4-octyne (Example 500); and 3-t-butoxy-4-cis-octenyl magnesium iodide was prepared from 3-t-butoxy-1-iodo-4-cis-octene (Example 501).

출처 및 근거

ORD 기록
ord-429efbe3d5644d258bd503ea5de156b4
출처 데이터셋
uspto-grants-1977_11
특허 번호
US04060540

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