Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Thionyl Chloride → 1-(Chloromethyl)pyrene
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Thionyl Chloride | HCID 24386 | — |
| 반응물 | 1-Pyrenemethanol | HCID 104977 | — |
| 용매 | Benzene | HCID 241 | — |
| 생성물 | 1-(Chloromethyl)pyrene | HCID 97581 | — |
반응 단계
Thionyl chloride (15 mL, 200 mmol) was added dropwise to a suspension of 1-hydroxymethylpyrene (9.3 g, 40 mmol) in dry benzene (150 mL) at 0° C. and the mixture was stirred at room temperature overnight. Evaporation of the solvent under reduced pressure gave a creamy-white solid, m.p. 146°-148° C., yield: 9.6 g, 96%.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05498549 |
| 출처 데이터셋 | uspto-grants-1996_03 |
| ORD ID | ord-81efd5c907df4757a011c283c9f9299a |
| 출처 메모 | uspto-grants-1996_03 |