참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Vinyl Acetate | HCID 7904 | — |
| 반응물 | Benzenecarbodithioic acid | HCID 67141 | — |
| 용매 | Carbon Tetrachloride | HCID 5943 | — |
| 생성물 | 1-Acetoxyethyl dithiobenzoate | HCID 9942835 | 51.5% |
반응 단계
A mixture of dithiobenzoic acid (4 g), vinyl acetate (10 mL) and carbon tetrachloride (15 mL) was heated at 70° C. for 16 hours. The resultant mixture was reduced and the residue purified by column chromatography (aluminium oxide column (activity III), n-hexane eluent) to give 1-acetoxyethyl dithiobenzoate (6) (3.21 g, 51.5% yield) as a dark red oil. 1H-nmr (CDCl3) d (ppm): 1.80 (d, 3H); 2.09 (s, 3H); 6.75 (q, 1H); 7.34-7.60 (m, 3H) and 7.97 (m, 2H).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US07666962B2 |
|---|
| 출처 데이터셋 | uspto-grants-2010_02 |
|---|
| ORD ID | ord-68416af82c3c41858b8d67d0e4c1c73e |
|---|
| 출처 메모 | uspto-grants-2010_02 |
|---|
