Peracetic Acid → Phenyl acetate

HRID 1447205

반응식

HRID 1447205 반응식
[C:1]([O-:4])(=[O:3])[CH3:2].[C:5]1([Sn+](C2C=CC=CC=2)C2C=CC=CC=2)[CH:10]=[CH:9][CH:8]=[CH:7][CH:6]=1.CC(O[Hg]C1C=CC=CC=1)=O.C(OO)(=O)C>>[C:1]([O:4][C:5]1[CH:10]=[CH:9][CH:8]=[CH:7][CH:6]=1)(=[O:3])[CH3:2]

참가 물질

4

반응물 3

HCID 6585Peracetic AcidHCID 9909408Triphenyltin hydroxide acetateHCID 16682730Phenylmercuric Acetate

생성물 1

HCID 31229Phenyl acetate수율 58%

실험 절차

The procedure of Example 1 is repeated except that 5 mmols of triphenyl tin acetate are employed instead of the phenyl mercuric acetate of Example 1, and 30 mmols of peracetic acid is used. After 4 hours of reaction at 75° C. there is obtained phenyl acetate in a yield of about 58%, and in a selectivity of about 68%, at a triphenyl tin acetate conversion of about 85%.

후처리

  1. customAfter 4 hours of reaction at 75° C.

출처 및 근거

ORD 기록
ord-bcd2cb51e5d4489f8c3c5766013152bd
출처 데이터셋
uspto-grants-1982_02
특허 번호
US04316045

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