1-Decanol → Magnesium decanolate

HRID 1447774노트

반응식

HRID 1447774 반응식
C([O-])(C)C.[Mg+2:5].C([O-])(C)C.[Mg].[CH2:11]([OH:21])[CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH3:20]>C(O[Ti](OCCCC)(OCCCC)OCCCC)CCC.C(O)(C)C>[CH2:11]([O-:21])[CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH3:20].[CH2:11]([O-:21])[CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH3:20].[Mg+2:5]

참가 물질

6

반응물 3

HCID 81741-DecanolHCID 5462224Magnesium2회HCID 10197750Magnesium dipropan-2-olate

생성물 1

HCID 21149434Magnesium decanolate

시약·촉매·용매 2

HCID 178454852HCID 178454852, 화합물촉매HCID 3776Isopropanol용매

실험 절차

If magnesium isopropanolate, together with e.g., 20 moles % of tetrabutoxy titanium, with respect to the amount of magnesium, and one or two equivalents of decanol, is introduced into an organic solvent, and the mixture is heated, a desirably low-viscosity solution of magnesium isopropanolatedecanolate, and/or of magnesium didecanolate, is formed, from which the liberated isopropanol can now readily be evaporated so as to achieve substantially full completion of the reaction.

후처리

  1. temperaturethe mixture is heated

출처 및 근거

ORD 기록
ord-e1e9c9fb7ba042fb99b0bb40dead3839
출처 데이터셋
uspto-grants-1979_12
특허 번호
US04178300

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