Formaldehyde → Methyl 2-(3-formyl-4-hydroxyphenyl)acetate

HRID 1454500

반응식

[OH:1][C:2]1[CH:7]=[CH:6][C:5]([CH2:8][C:9]([O:11][CH3:12])=[O:10])=[CH:4][CH:3]=1.[CH2:13]=[O:14]>>[CH:13]([C:7]1[CH:6]=[C:5]([CH2:8][C:9]([O:11][CH3:12])=[O:10])[CH:4]=[CH:3][C:2]=1[OH:1])=[O:14]

참가 물질

반응물 2

HCID 712Formaldehyde

HCID 518900Benzeneacetic acid, 4-hydroxy-, methyl ester

생성물 1

HCID 12374099Methyl 2-(3-formyl-4-hydroxyphenyl)acetate수율 100%

실험 절차

Proceeding as in Reference 8, but substituting methyl 4-hydroxyphenylacetate (42.9 g, 0.258 mol) and paraformaldehyde (77.5 g, 2.58 mole), gave methyl 3-formyl-4-hydroxy-phenyl-acetate (50.0 g, ˜100%).

출처 및 근거

ORD 기록: ord-9fb45d5732b54a7890f866b5ec7d2bc4
출처 데이터셋: uspto-grants-2009_01
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US07479502B2

연결된 노트

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