Perfluorocyclopentene → 1H,2H-Octafluorocyclopentane
반응식
[F:1][C:2]1([F:13])[C:6]([F:7])=[C:5]([F:8])[C:4]([F:10])([F:9])[C:3]1([F:12])[F:11]>[Pd]>[F:8][CH:5]1[C:4]([F:9])([F:10])[C:3]([F:11])([F:12])[C:2]([F:1])([F:13])[CH:6]1[F:7]참가 물질
3
실험 절차
Then a reactor was charged with 12 g of the octafluorocyclopentene and 0.24 g of a 5%-palladium/carbon catalyst and hydrogenation was conducted at a temperature of 50° C. and a hydrogenation pressure of 6 kg/cm2. When the absorption of hydrogen ceased, the reaction was completed. After the removal of the catalyst and the produced hydrogen fluoride from the reaction mixture, the reaction mixture was distilled to give 9 g of 1,2,3,3,4,4,5,5-octafluorocyclopentane (b.p., 79° C.; purity, 99%).
후처리
- customwas conducted at a temperature of 50° C.
- customWhen the absorption of hydrogen
- customAfter the removal of the catalyst
- distillationthe produced hydrogen fluoride from the reaction mixture, the reaction mixture was distilled
출처 및 근거
- ORD 기록
- ord-584f96472ccb4403bff642ff424fa547
- 출처 데이터셋
- uspto-grants-1998_12
- 특허 번호
- US05847243
반응 노트
불러오는 중…