4-tert-Butylbenzyl alcohol → HCID 57118008, 화합물

HRID 1458194

반응식

HRID 1458194 반응식
[C:1](Cl)(=[O:5])[C:2]([Cl:4])=[O:3].[C:7]([C:11]1[CH:18]=[CH:17][C:14]([CH2:15][OH:16])=[CH:13][CH:12]=1)([CH3:10])([CH3:9])[CH3:8]>C(OCC)C>[C:7]([C:11]1[CH:12]=[CH:13][C:14]([CH2:15][O:16][C:1](=[O:5])[C:2]([Cl:4])=[O:3])=[CH:17][CH:18]=1)([CH3:10])([CH3:8])[CH3:9]

참가 물질

4

반응물 2

HCID 134164-tert-Butylbenzyl alcoholHCID 65578Oxalyl chloride

생성물 1

HCID 57118008HCID 57118008, 화합물

시약·촉매·용매 1

HCID 3283Diethyl Ether용매2회

실험 절차

To a stirred solution of oxalyl dichloride (100ml) in diethylether (500 ml) at -10° under nitrogen a solution of 4-t-butylbenzyl alcohol (200 ml) in diethylether (100 ml) was added dropwise so as to maintain the temperature between -10° and -5°. The solvent was then evaporated under vacuum to give the title compound (289 g,) as a clear oil (b.p. 120°-122° at 2 mbar).

후처리

  1. temperatureto maintain the temperature between -10° and -5°
  2. customThe solvent was then evaporated under vacuum

출처 및 근거

ORD 기록
ord-552cfa4c7d574c2cae876c5253dbc6fa
출처 데이터셋
uspto-grants-1998_12
특허 번호
US05849907

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