Methanol → 2,5-Undecadien-1-ol, (2Z,5Z)-
반응식
[CH3:1][OH:2].[CH2:3]1[CH2:8][CH2:7][CH2:6][CH2:5][CH2:4]1>[Pd]>[CH2:1]([OH:2])/[CH:8]=[CH:3]\[CH2:4]/[CH:5]=[CH:3]\[CH2:8][CH2:7][CH2:6][CH2:5][CH3:4]참가 물질
4
실험 절차
6.2 G (37.8 mmole) of the carbinol obtained as indicated under letter i. above, dissolved in 50 ml of cyclohexane, were hydrogenated at atmospheric pressure in the presence of 120 mg of Lindlar type palladium catalyst. After filtration and evaporation, the obtained residue was chromatographed on a silica column, using as eluting agent a mixture of 1 to 10% ethyl acetate in cyclohexane, to give 5.9 g (yield: 95%) of undeca-2Z,5Z-dienol.
후처리
- filtrationAfter filtration and evaporation
- customthe obtained residue was chromatographed on a silica column
- washas eluting agent
- additiona mixture of 1 to 10% ethyl acetate in cyclohexane
출처 및 근거
- ORD 기록
- ord-229acd8452ee4a1abbba2eefc2915cad
- 출처 데이터셋
- uspto-grants-1994_04
- 특허 번호
- US05300716
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