Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Triphenylphosphine → [4-(Benzyloxy)benzyl](triphenyl)phosphonium chloride
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Triphenylphosphine | HCID 11776 | — |
| 반응물 | 4-Benzyloxybenzyl chloride | HCID 70042 | — |
| 용매 | Toluene | HCID 1140 | — |
| 생성물 | [4-(Benzyloxy)benzyl](triphenyl)phosphonium chloride | HCID 383834 | 88.1% |
반응 단계
To a suspension of 1-(benzyloxy)-4-(chloromethyl)benzene (4.890 g, 21.01 mmol) in toluene (25 ml) was added triphenylphosphine (6.617 g, 25.23 mmol). The mixture was heated under reflux for 24 hrs, and cooled to room temperature. The precipitate was collected by filtration, and dried under reduced pressure to give [4-(benzyloxy)benzyl](triphenyl)phosphonium chloride (9.166 g, yield 88.1%) as a white solid.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US08999989B2 |
| 출처 데이터셋 | uspto-grants-2015_04 |
| ORD ID | ord-813e6d3b514547329678200b2299595c |
| 출처 메모 | uspto-grants-2015_04 |