Formaldehyde → Tert-butyltriazine

HRID 1488326

반응식

HRID 1488326 반응식
[NH:1]1[CH2:6][CH2:5][CH2:4][NH:3][NH:2]1.[C:7](N)([CH3:10])([CH3:9])[CH3:8].C=O>>[C:7]([C:6]1[CH:5]=[CH:4][N:3]=[N:2][N:1]=1)([CH3:10])([CH3:9])[CH3:8]

참가 물질

4

반응물 3

HCID 712Formaldehyde2회HCID 6385Tert-ButylamineHCID 160486341,2,3-Triazinane

생성물 1

HCID 22904584Tert-butyltriazine수율 90%

실험 절차

In carrying out the reaction to prepare the preferred hexahydro-triazine, the tert-butylamine is added slowly to a concentrated aqueous solution of the formaldehyde (formalin) and the stoichiometry is maintained to so that there is an exact equivalent to a slight excess of the amine at the end of the reaction. Typically, a molar ratio of at least 1.00 to 1.05 of the amine to the formaldehyde is preferred for the overall process to form the tert-butyltriazine quantitatively (in excess of 90% yield). For the reaction to go to completion satisfactorily and to yield the tert-butyltriazine, careful control of the reaction conditions must be observed in order to avoid side-reactions. During the slow addition of the amine it is desirable to maintain a reaction temperature below 46° C.

후처리

  1. customthe reaction
  2. temperaturethe stoichiometry is maintained to so that there
  3. customat the end of the reaction

출처 및 근거

ORD 기록
ord-f3af9a33c24a41189590164c8bc81d97
출처 데이터셋
uspto-grants-1997_10
특허 번호
US05674377

연결된 노트

불러오는 중…