Phosphorus trichloride → Isododecyl chloride

HRID 1489496

반응식

P(Cl)(Cl)[Cl:2].[CH2:5](O)[CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH:14]([CH3:16])[CH3:15]>>[CH2:5]([Cl:2])[CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH:14]([CH3:16])[CH3:15]

참가 물질

반응물 2

HCID 24387Phosphorus trichloride

HCID 6428591Isododecanol

생성물 1

HCID 22901855Isododecyl chloride수율 256.7%

실험 절차

To a 1-gallon glass-line pressure reactor was charged 715 grams of phosphorus trichloride (PCl3, 5.2 moles). To the reactor was charged 2790 grams of isododecyl alcohol (Exxal 12, 15.0 moles) via an addition pump over a period of one hour while maintaining the reaction temperature below 100° C. After addition, the mixture was stirred at 130°-135° C. for 3 hours and cooled. The top organic layer was collected, yielding 2733 grams (94.5%) of isododecyl chloride.

후처리

temperaturewhile maintaining the reaction temperature below 100° C
additionAfter addition
temperaturecooled
customThe top organic layer was collected

출처 및 근거

ORD 기록: ord-22b0b20d138b465b9ab56e230416995e
출처 데이터셋: uspto-grants-1997_10
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US05679633

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