Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Phenol → Diphenyl carbonate
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Phenol | HCID 996 | — |
| 반응물 | Phenyl chloroformate | HCID 15891 | — |
| 촉매 | Titanium mononitride | HCID 93091 | — |
| 생성물 | Diphenyl carbonate | HCID 7597 | — |
반응 단계
Example 1 was repeated with 14.1 g of a powdered titanium nitride from H. C. Starck at 140° C. After 2 hours' reaction time, phenol conversion was 21.6%, wherein 0.03 g of phenyl chloroformate and 34.3 g of diphenyl carbonate were formed. Selectivity for carbonates was approximately 99%.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05679825 |
| 출처 데이터셋 | uspto-grants-1997_10 |
| ORD ID | ord-30e6626a19f74b55b2109bb371db2ccb |
| 출처 메모 | uspto-grants-1997_10 |