5-Methoxy-2-methylbenzoxazole → 5-Methoxy-2-methyl-7-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1,3-benzoxazole

HRID 1490442

반응식

HRID 1490442 반응식
COc1ccc2oc(C)nc2c1>C1=CCCC=CCC1.C1=CCCC=CCC1.C1CCOC1.CC1(C)OB(B2OC(C)(C)C(C)(C)O2)OC1(C)C.C[OH2+].C[OH2+].Cc1cnc2c(ccc3c(C)c(C)cnc32)c1C.[Ir].[Ir]>COc1cc(B2OC(C)(C)C(C)(C)O2)c2oc(C)nc2c1

참가 물질

6

반응물 1

HCID 797595-Methoxy-2-methylbenzoxazole

생성물 1

HCID 1018796725-Methoxy-2-methyl-7-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1,3-benzoxazole수율 81%

시약·촉매·용매 4

HCID 742653,4,7,8-Tetramethyl-1,10-phenanthroline시약HCID 2733548Bis(pinacolato)diborane시약HCID 76001521Bis(1,5-cyclooctadiene)dimethoxydiiridium촉매HCID 8028Tetrahydrofuran용매

반응 조건

온도
25 °C

출처 및 근거

ORD 기록
ord-55e88a31e2674dffa1d0d739f94bb7f9
출처 데이터셋
Borylation dataset from Roche

연결된 노트

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