2-p-Tolylbenzoxazole → 2-(4-Methylphenyl)-7-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1,3-benzoxazole

HRID 1490446

반응식

HRID 1490446 반응식
Cc1ccc(-c2nc3ccccc3o2)cc1>C1=CCCC=CCC1.C1=CCCC=CCC1.C1CCOC1.CC1(C)OB(B2OC(C)(C)C(C)(C)O2)OC1(C)C.C[OH2+].C[OH2+].Cc1cnc2c(ccc3c(C)c(C)cnc32)c1C.[Ir].[Ir]>Cc1ccc(-c2nc3cccc(B4OC(C)(C)C(C)(C)O4)c3o2)cc1

참가 물질

6

반응물 1

HCID 700392-p-Tolylbenzoxazole

생성물 1

HCID 1018796742-(4-Methylphenyl)-7-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1,3-benzoxazole수율 71%

시약·촉매·용매 4

HCID 742653,4,7,8-Tetramethyl-1,10-phenanthroline시약HCID 2733548Bis(pinacolato)diborane시약HCID 76001521Bis(1,5-cyclooctadiene)dimethoxydiiridium촉매HCID 8028Tetrahydrofuran용매

반응 조건

온도
25 °C

출처 및 근거

ORD 기록
ord-007e8eef70bb4226ba7c3472404c4905
출처 데이터셋
Borylation dataset from Roche

연결된 노트

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