2-Methylbenzothiazole → HCID 72221079, 화합물

HRID 1490450노트

반응식

HRID 1490450 반응식
Cc1nc2ccccc2s1>C1=CCCC=CCC1.C1=CCCC=CCC1.C1CCOC1.CC1(C)OB(B2OC(C)(C)C(C)(C)O2)OC1(C)C.C[OH2+].C[OH2+].Cc1cnc2c(ccc3c(C)c(C)cnc32)c1C.[Ir].[Ir]>Cc1nc2ccc(B3OC(C)(C)C(C)(C)O3)cc2s1.Cc1nc2cccc(B3OC(C)(C)C(C)(C)O3)c2s1

참가 물질

7

반응물 1

HCID 84462-Methylbenzothiazole

생성물 2

HCID 208163372-Methylbenzo[d]thiazol-6-ylboronic acid pinacol ester수율 9%HCID 72221079HCID 72221079, 화합물수율 24%

시약·촉매·용매 4

HCID 742653,4,7,8-Tetramethyl-1,10-phenanthroline시약HCID 2733548Bis(pinacolato)diborane시약HCID 76001521Bis(1,5-cyclooctadiene)dimethoxydiiridium촉매HCID 8028Tetrahydrofuran용매

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온도
50 °C

출처 및 근거

ORD 기록
ord-4f3c78f3989945ffb77525be1fcde576
출처 데이터셋
Borylation dataset from Roche

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