1-(Triisopropylsilyl)indole → HCID 11395451, 화합물
반응식
CC(C)[Si](C(C)C)(C(C)C)n1ccc2ccccc21>B1Oc2ccccc2O1.CC(C)(O)C(C)(C)O.CCN(CC)CC.Cc1ccccc1.Fc1c(F)c(F)c(B(c2c(F)c(F)c(F)c(F)c2F)c2c(F)c(F)c(F)c(F)c2F)c(F)c1F>CC(C)[Si](C(C)C)(C(C)C)n1cc(B2OC(C)(C)C(C)(C)O2)c2ccccc21참가 물질
7
반응 조건
- 온도
- 120 °C
실험 절차
Prepared from N-(triisopropylsilyl)-1H-indole (4a, 54.7 mg, 0.200 mmol, 1.00 equiv) and catBH (96.0 mg, 0.800 mmol, 4.00 equiv) according to GP 2. The title compound was purified by flash column chromatography using cyclohexane/EtOAc/Et3N (30/1/1) as eluent to afford 6a (50.3 mg, 63%) as a slightly yellow oil.
출처 및 근거
- ORD 기록
- ord-60618b7fc5b54d599ac4309f26d5cb76
- 출처 데이터셋
- Borylation dataset from Roche
반응 노트
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