2-Phenylindole → 2-Phenyl-7-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-YL)-1H-indole

HRID 1490584노트

반응식

HRID 1490584 반응식
c1ccc(-c2cc3ccccc3[nH]2)cc1>C1=CCCC=CCC1.C1=CCCC=CCC1.CC(C)(C)c1ccnc(-c2cc(C(C)(C)C)ccn2)c1.CC1(C)OBOC1(C)C.CCCCCC.C[OH2+].C[OH2+].[Ir].[Ir]>CC1(C)OB(c2cccc3cc(-c4ccccc4)[nH]c23)OC1(C)C

참가 물질

6

반응물 1

HCID 136982-Phenylindole

생성물 1

HCID 249609632-Phenyl-7-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-YL)-1H-indole수율 69%

시약·촉매·용매 4

HCID 27347684,4,5,5-Tetramethyl[1,3,2]dioxaborolane시약HCID 42491874,4'-Di-tert-butyl-2,2'-bipyridyl시약HCID 76001521Bis(1,5-cyclooctadiene)dimethoxydiiridium촉매HCID 8058Hexane용매

반응 조건

온도
60 °C

출처 및 근거

ORD 기록
ord-edbac54e57af4c27962644d83ee14132
출처 데이터셋
Borylation dataset from Roche

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