Benzaldehyde → 2-Formylphenylboronic acid pinacol ester

HRID 1490616노트

반응식

HRID 1490616 반응식
O=Cc1ccccc1>C1=CCCC=CCC1.C1=CCCC=CCC1.C1CCOC1.CC(C)(C)N.CC1(C)OB(B2OC(C)(C)C(C)(C)O2)OC1(C)C.CC1(C)OBOC1(C)C.C[OH2+].C[OH2+].Nc1cccc2cccnc12.[Ir].[Ir]>CC1(C)OB(c2ccccc2C=O)OC1(C)C

참가 물질

8

반응물 1

HCID 240Benzaldehyde

생성물 1

HCID 109773222-Formylphenylboronic acid pinacol ester수율 87%

시약·촉매·용매 6

HCID 6385Tert-Butylamine시약HCID 113598-Aminoquinoline시약HCID 2733548Bis(pinacolato)diborane시약HCID 27347684,4,5,5-Tetramethyl[1,3,2]dioxaborolane시약HCID 76001521Bis(1,5-cyclooctadiene)dimethoxydiiridium촉매HCID 8028Tetrahydrofuran용매

반응 조건

온도
90 °C

출처 및 근거

ORD 기록
ord-c3bc362270de46efa26dac41e95f14aa
출처 데이터셋
Borylation dataset from Roche

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