Indole → 2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1H-indole

HRID 1490738노트

반응식

HRID 1490738 반응식
c1ccc2[nH]ccc2c1>C1=CCCC=CCC1.C1=CCCC=CCC1.C1CCOC1.CC1(C)OB(B2OC(C)(C)C(C)(C)O2)OC1(C)C.C[OH2+].C[OH2+].O=c1ccc2cccc(-c3ccc(-c4ccccn4)nc3)c2[nH]1.[Ir].[Ir]>CC1(C)OB(c2cc3ccccc3[nH]2)OC1(C)C

참가 물질

6

반응물 1

HCID 798Indole

생성물 1

HCID 113569352-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1H-indole수율 25%

시약·촉매·용매 4

HCID 2733548Bis(pinacolato)diborane시약HCID 1646813858-([2,2'-bipyridin]-5-yl)quinolin-2(1H)-one시약HCID 76001521Bis(1,5-cyclooctadiene)dimethoxydiiridium촉매HCID 8028Tetrahydrofuran용매

반응 조건

온도
80 °C

출처 및 근거

ORD 기록
ord-e2052b834d4f47a8bce5bc1268dbf810
출처 데이터셋
Borylation dataset from Roche

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