2-chloro-N,N-dihexylbenzamide → 2-chloro-N,N-dihexyl-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzamide

HRID 1490838노트

반응식

HRID 1490838 반응식
CCCCCCN(CCCCCC)C(=O)c1ccccc1Cl>C1=CCCC=CCC1.C1=CCCC=CCC1.CC(C)(C)c1ccnc(-c2cc(C(C)(C)C)ccn2)c1.CC1(C)OB(B2OC(C)(C)C(C)(C)O2)OC1(C)C.C[OH2+].C[OH2+].Cc1ccc(C)cc1.[Ir].[Ir]>CCCCCCN(CCCCCC)C(=O)c1cc(B2OC(C)(C)C(C)(C)O2)ccc1Cl.CCCCCCN(CCCCCC)C(=O)c1ccc(B2OC(C)(C)C(C)(C)O2)cc1Cl

참가 물질

7

반응물 1

HCID 43076702-chloro-N,N-dihexylbenzamide

생성물 2

HCID 91820793HCID 91820793, 화합물수율 38%HCID 1408473562-chloro-N,N-dihexyl-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzamide수율 61%

시약·촉매·용매 4

HCID 2733548Bis(pinacolato)diborane시약HCID 42491874,4'-Di-tert-butyl-2,2'-bipyridyl시약HCID 76001521Bis(1,5-cyclooctadiene)dimethoxydiiridium촉매HCID 7809P-Xylene용매

반응 조건

온도
25 °C

출처 및 근거

ORD 기록
ord-0337d2f5f87247f795d864efbda2616b
출처 데이터셋
Borylation dataset from Roche

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