Benzamide, N,N-dihexyl-2-trifluoromethyl- → N,N-dihexyl-2-(trifluoromethyl)-5-(4,4,6-trimethyl-1,3,2-dioxaborinan-2-yl)benzamide

HRID 1490858노트

반응식

HRID 1490858 반응식
CCCCCCN(CCCCCC)C(=O)c1ccccc1C(F)(F)F>C1=CCCC=CCC1.C1=CCCC=CCC1.CC(C)(C)c1ccnc(-c2cc(C(C)(C)C)ccn2)c1.CC1CC(C)(C)OB(B2OC(C)CC(C)(C)O2)O1.C[OH2+].C[OH2+].Cc1ccc(C)cc1.[Ir].[Ir]>CCCCCCN(CCCCCC)C(=O)c1cc(B2OC(C)CC(C)(C)O2)ccc1C(F)(F)F.CCCCCCN(CCCCCC)C(=O)c1ccc(B2OC(C)CC(C)(C)O2)cc1C(F)(F)F

참가 물질

7

반응물 1

HCID 533223Benzamide, N,N-dihexyl-2-trifluoromethyl-

생성물 2

HCID 122390934N,N-dihexyl-2-(trifluoromethyl)-5-(4,4,6-trimethyl-1,3,2-dioxaborinan-2-yl)benzamide수율 29%HCID 178444786HCID 178444786, 화합물수율 27%

시약·촉매·용매 4

HCID 2734616Bis(hexylene Glycolato)diboron시약HCID 42491874,4'-Di-tert-butyl-2,2'-bipyridyl시약HCID 76001521Bis(1,5-cyclooctadiene)dimethoxydiiridium촉매HCID 7809P-Xylene용매

반응 조건

온도
25 °C

출처 및 근거

ORD 기록
ord-5a5f1209465342a0841cc4b7df0292b6
출처 데이터셋
Borylation dataset from Roche

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