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1-Tetralone → 6-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)-3,4-dihydronaphthalen-1(2H)-one

HRID 1490933
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인쇄 미리보기

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HRID 1490933 반응식
O=C1CCCc2ccccc21>C1=CCCC=CCC1.C1=CCCC=CCC1.CC(C)(C)c1ccnc(-c2cc(C(C)(C)C)ccn2)c1.CC1(C)OB(B2OC(C)(C)C(C)(C)O2)OC1(C)C.COC(C)(C)C.C[OH2+].C[OH2+].[Ir].[Ir]>CC1(C)OB(c2ccc3c(c2)C(=O)CCC3)OC1(C)C.CC1(C)OB(c2ccc3c(c2)CCCC3=O)OC1(C)C
참가 물질반응 조건실험 절차출처 및 근거반응 노트

참가 물질

7

반응물 1

HCID 107241-Tetralone

생성물 2

HCID 68473465HCID 68473465, 화합물수율 20%HCID 713038396-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)-3,4-dihydronaphthalen-1(2H)-one수율 80%

시약·촉매·용매 4

HCID 2733548Bis(pinacolato)diborane시약HCID 42491874,4'-Di-tert-butyl-2,2'-bipyridyl시약HCID 76001521Bis(1,5-cyclooctadiene)dimethoxydiiridium촉매HCID 15413tert-Butyl methyl ether용매

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온도
25 °C

실험 절차

General procedure Dwas applied to 3,4-dihydronaphthalen-1(2H)-one15i(29mg, 0.2mmol). The reactionmixture was allowed to stand for 16hoursgiving a conversion of >99% (GC-MS) and 16iand 17iin a 80:20mixture (1H NMR spectrum).

출처 및 근거

ORD 기록
ord-f3741a9c10d54b95a8a57098ee379e4e
출처 데이터셋
Borylation dataset from Roche
DOI
10.1039/c2sc20776a

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