Thioanisole → 2-Methylsulfanylphenylboronic acid, pinacol ester

HRID 1491128노트

반응식

HRID 1491128 반응식
CSc1ccccc1>C1=CCCC=CCC1.C1=CCCC=CCC1.CC1(C)OB(B2OC(C)(C)C(C)(C)O2)OC1(C)C.C[OH2+].C[OH2+].Cc1ccc(C)cc1.FC(F)(F)C1COB(c2ccccc2-c2ccc(-c3ccccn3)nc2)O1.[Ir].[Ir]>CSc1ccccc1B1OC(C)(C)C(C)(C)O1

참가 물질

6

반응물 1

HCID 7520Thioanisole

생성물 1

HCID 177502722-Methylsulfanylphenylboronic acid, pinacol ester수율 64%

시약·촉매·용매 4

HCID 2733548Bis(pinacolato)diborane시약HCID 1349566232-Pyridin-2-yl-5-[2-[4-(trifluoromethyl)-1,3,2-dioxaborolan-2-yl]phenyl]pyridine시약HCID 76001521Bis(1,5-cyclooctadiene)dimethoxydiiridium촉매HCID 7809P-Xylene용매

반응 조건

온도
55 °C

출처 및 근거

ORD 기록
ord-3e865c2d98c64f528b92861f9578b974
출처 데이터셋
Borylation dataset from Roche

반응 노트

불러오는 중…