참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | (Ethylthio)benzene | HCID 12144 | — |
| 시약 | 4,4'-Dimethyl-2,2'-bipyridine | HCID 14338 | — |
| 시약 | Bis(pinacolato)diborane | HCID 2733548 | — |
| 촉매 | Bis(1,5-cyclooctadiene)dimethoxydiiridium | HCID 76001521 | — |
| 용매 | P-Xylene | HCID 7809 | — |
| 생성물 | 2-(2-(Ethylthio)phenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane | HCID 123787969 | 24% |
| 생성물 | HCID 178477269 | HCID 178477269 | 30% |
반응 단계
dtbpy: The mixture of product (110 mg, 83% yield, ortho/meta + para = 0.29); meta- and para- isomers (5b+5bʹ) were obtained by further purification of the crude mixture by GPC (77 mg, 58% yield), colorless oil;
출처 및 근거
| DOI | 10.1002/anie.201610041 |
|---|
| 출처 데이터셋 | Borylation dataset from Roche |
|---|
| ORD ID | ord-3cf848853d454210a4ad7b64186a1c6e |
|---|
| 출처 메모 | Borylation dataset from Roche |
|---|
