Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
HRID 1491145생성일: 2026년 10월 26일
3-Methoxythioanisole → 2-(3-Methoxy-5-(methylthio)phenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
https://huagongshe.com/reaction/1491145
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | 3-Methoxythioanisole | HCID 281182 | — |
| 시약 | 4,4'-Dimethyl-2,2'-bipyridine | HCID 14338 | — |
| 시약 | Bis(pinacolato)diborane | HCID 2733548 | — |
| 촉매 | Bis(1,5-cyclooctadiene)dimethoxydiiridium | HCID 76001521 | — |
| 용매 | P-Xylene | HCID 7809 | — |
| 생성물 | 2-(3-Methoxy-5-(methylthio)phenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane | HCID 53217246 | 69% |
반응 단계
dtbpy: A mixture of ortho- and meta-borylated products (97 mg, 69% yield, ortho/meta + para = <0.01); meta-Isomer 5i were obtained by further purification by GPC (92 mg, 66% yield), white solid (mp. 73-75 oC)
출처 및 근거
| DOI | 10.1002/anie.201610041 |
|---|
| 출처 데이터셋 | Borylation dataset from Roche |
|---|
| ORD ID | ord-bc30bcc9f8fa4078b52bc21fad6778ea |
|---|
| 출처 메모 | Borylation dataset from Roche |
|---|
