3-Ethyl-(1-thiaethyl)-benzene → HCID 164891978, 화합물

HRID 1491149노트

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HRID 1491149 반응식
CCc1cccc(SC)c1>C1=CCCC=CCC1.C1=CCCC=CCC1.CC1(C)OB(B2OC(C)(C)C(C)(C)O2)OC1(C)C.C[OH2+].C[OH2+].Cc1ccc(C)cc1.Cc1ccnc(-c2cc(C)ccn2)c1.[Ir].[Ir]>CCc1cc(SC)cc(B2OC(C)(C)C(C)(C)O2)c1

참가 물질

6

반응물 1

HCID 149441333-Ethyl-(1-thiaethyl)-benzene

생성물 1

HCID 164891978HCID 164891978, 화합물수율 74%

시약·촉매·용매 4

HCID 143384,4'-Dimethyl-2,2'-bipyridine시약HCID 2733548Bis(pinacolato)diborane시약HCID 76001521Bis(1,5-cyclooctadiene)dimethoxydiiridium촉매HCID 7809P-Xylene용매

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온도
55 °C

실험 절차

Yield: A mixture of ortho- and meta-borylated products (103 mg, 74% yield, ortho/meta + para = <0.01); meta-Isomer 5k was obtained by further purification by GPC (93 mg, 67% yield), colorless oil;

출처 및 근거

ORD 기록
ord-07735c61c2ba4303a5458fefe94b7ddd
출처 데이터셋
Borylation dataset from Roche

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