참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Methyl 3-(methylthio)benzoate | HCID 6432769 | — |
| 시약 | 4,4'-Dimethyl-2,2'-bipyridine | HCID 14338 | — |
| 시약 | Bis(pinacolato)diborane | HCID 2733548 | — |
| 촉매 | Bis(1,5-cyclooctadiene)dimethoxydiiridium | HCID 76001521 | — |
| 용매 | P-Xylene | HCID 7809 | — |
| 생성물 | HCID 178498626 | HCID 178498626 | 83% |
반응 단계
dtbpy: A mixture of ortho- and meta-borylated products (128 mg, 83% yield, ortho/meta + para = <0.01); meta-Isomer 5pwas obtained by further purification by GPC (116 mg, 75% yield), white solid (mp. 115-117 oC)
출처 및 근거
| DOI | 10.1002/anie.201610041 |
|---|
| 출처 데이터셋 | Borylation dataset from Roche |
|---|
| ORD ID | ord-76f3f83feb2744bb84a39a38dd5be253 |
|---|
| 출처 메모 | Borylation dataset from Roche |
|---|
