1,3-Diisopropylbenzene → 2-[3,5-Di(propan-2-yl)phenyl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

HRID 1491244

반응식

HRID 1491244 반응식
CC(C)c1cccc(C(C)C)c1>C1=CCCC=CCC1.C1=CCCC=CCC1.C1CCOC1.CC(C)(C)c1ccnc(-c2cc(C(C)(C)C)ccn2)c1.CC1(C)OB(B2OC(C)(C)C(C)(C)O2)OC1(C)C.C[OH2+].C[OH2+].[Ir].[Ir]>CC(C)c1cc(B2OC(C)(C)C(C)(C)O2)cc(C(C)C)c1

참가 물질

6

반응물 1

HCID 74501,3-Diisopropylbenzene

생성물 1

HCID 534290492-[3,5-Di(propan-2-yl)phenyl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane수율 83%

시약·촉매·용매 4

HCID 2733548Bis(pinacolato)diborane시약HCID 42491874,4'-Di-tert-butyl-2,2'-bipyridyl시약HCID 76001521Bis(1,5-cyclooctadiene)dimethoxydiiridium촉매HCID 8028Tetrahydrofuran용매

반응 조건

온도
25 °C

출처 및 근거

ORD 기록
ord-bac43139b767409ebec942f4b010d100
출처 데이터셋
Borylation dataset from Roche

연결된 노트

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