1-(2-Methoxyphenyl)isoquinoline → 1-[2-Methoxy-6-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]isoquinoline
반응식
COc1ccccc1-c1nccc2ccccc12>C(=NN(Cc1ccccc1)Cc1ccccc1)c1ccccn1.C1=CCCC=CCC1.C1=CCCC=CCC1.C1CCOC1.CC1(C)OB(B2OC(C)(C)C(C)(C)O2)OC1(C)C.CC1(C)OBOC1(C)C.C[OH2+].C[OH2+].[Ir].[Ir]>COc1cccc(B2OC(C)(C)C(C)(C)O2)c1-c1nccc2ccccc12참가 물질
7
반응물 1
생성물 1
시약·촉매·용매 5
반응 조건
- 온도
- 50 °C
실험 절차
Following the general procedure, precipitation from the reaction crude with hexane and trituration afforded 9i (159 mg, 88 %) as a pale solid.
출처 및 근거
- ORD 기록
- ord-2dd73b1c305947e1a593c90545f7d2d2
- 출처 데이터셋
- Borylation dataset from Roche
반응 노트
불러오는 중…