4-Chlorobenzaldehyde 2,2-dimethylhydrazone → HCID 178484938, 화합물

HRID 1491502노트

반응식

HRID 1491502 반응식
CN(C)N=Cc1ccc(Cl)cc1>C(=NN(Cc1ccccc1)Cc1ccccc1)c1ccccn1.C1=CCCC=CCC1.C1=CCCC=CCC1.C1CCOC1.CC1(C)OB(B2OC(C)(C)C(C)(C)O2)OC1(C)C.CC1(C)OBOC1(C)C.C[OH2+].C[OH2+].[Ir].[Ir]>CN(C)N=Cc1ccc(Cl)cc1B1OC(C)(C)C(C)(C)O1

참가 물질

7

반응물 1

HCID 2112214-Chlorobenzaldehyde 2,2-dimethylhydrazone

생성물 1

HCID 178484938HCID 178484938, 화합물수율 73%

시약·촉매·용매 5

HCID 2733548Bis(pinacolato)diborane시약HCID 27347684,4,5,5-Tetramethyl[1,3,2]dioxaborolane시약HCID 67601456N,N-Dibenzyl-N'-(pyridin-2-ylmethylene)hydrazine시약HCID 76001521Bis(1,5-cyclooctadiene)dimethoxydiiridium촉매HCID 8028Tetrahydrofuran용매

반응 조건

온도
80 °C

실험 절차

Following the general procedure, column chromatography in neutral alumina (EtOAc/n-hexane 1:10) afforded 11g (112 mg, 73 %).

출처 및 근거

ORD 기록
ord-4f76430a1a884af5b1fb0714cab85713
출처 데이터셋
Borylation dataset from Roche

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