1,1-Dimethyl-2-[(naphthalen-1-yl)methylidene]hydrazine → HCID 178484931, 화합물

반응식

CN(C)N=Cc1cccc2ccccc12>C(=NN(Cc1ccccc1)Cc1ccccc1)c1ccccn1.C1=CCCC=CCC1.C1=CCCC=CCC1.C1CCOC1.CC1(C)OB(B2OC(C)(C)C(C)(C)O2)OC1(C)C.CC1(C)OBOC1(C)C.C[OH2+].C[OH2+].[Ir].[Ir]>CN(C)N=Cc1c(B2OC(C)(C)C(C)(C)O2)ccc2ccccc12

참가 물질

반응 조건

온도: 80 °C

실험 절차

Following the general procedure, column chromatography in neutral alumina (EtOAc/n-hexane 1:8) afforded 11i (155 mg, 95 %) as a yellow oil.

출처 및 근거

ORD 기록: ord-04ef4005b699487e9a1d97d3cb0cd4bf
출처 데이터셋: Borylation dataset from Roche
DOI: 10.1002/anie.201104544

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참가 물질

반응물 1

HCID 3005081,1-Dimethyl-2-[(naphthalen-1-yl)methylidene]hydrazine

생성물 1

HCID 178484931HCID 178484931, 화합물수율 95%

시약·촉매·용매 5

HCID 2733548Bis(pinacolato)diborane시약

HCID 27347684,4,5,5-Tetramethyl[1,3,2]dioxaborolane시약

HCID 67601456N,N-Dibenzyl-N'-(pyridin-2-ylmethylene)hydrazine시약

HCID 76001521Bis(1,5-cyclooctadiene)dimethoxydiiridium촉매

HCID 8028Tetrahydrofuran용매

반응 조건

온도: 80 °C

실험 절차

Following the general procedure, column chromatography in neutral alumina (EtOAc/n-hexane 1:8) afforded 11i (155 mg, 95 %) as a yellow oil.

출처 및 근거

ORD 기록: ord-04ef4005b699487e9a1d97d3cb0cd4bf
출처 데이터셋: Borylation dataset from Roche
DOI: 10.1002/anie.201104544

반응 노트

불러오는 중…