Sodium methanethiolate → HCID 12882536, 화합물
반응식
F[C:2]1[CH:11]=[C:10]([S:12][CH3:13])[CH:9]=[CH:8][C:3]=1[C:4]([O:6][CH3:7])=[O:5].[CH3:14][S-:15].[Na+]>CN(C)C=O>[CH3:14][S:15][C:2]1[CH:11]=[C:10]([S:12][CH3:13])[CH:9]=[CH:8][C:3]=1[C:4]([O:6][CH3:7])=[O:5]참가 물질
4
반응 조건
- 온도
- 50 °C
실험 절차
A mixture of methyl 2-fluoro-4-methylsulphenylbenzoate (4.1 g), sodium thiomethoxide (1.48 g) and N,N-dimethylformamide (16 ml) was stirred at 50° C. for 18 hours, poured onto water and extracted (ethyl acetate). The extract was washed (water), dried (magnesium sulphate) and evaporated to give methyl 2-methylsulphenyl-4-methylsulphenylbenzoate (2.09 g) as an orange oil, NMR (CDCl3) 2.0 (s,3H), 2.4 (s,3H), 3.65 (s,2H), 3.9 (s,3H), 7.05 (dd,1H), 7.15 (d,1H), 7.9 (d,1H).
후처리
- additionpoured onto water
- extractionextracted (ethyl acetate)
- washThe extract was washed (water)
- dry with materialdried (magnesium sulphate)
- customevaporated
출처 및 근거
- ORD 기록
- ord-917cc09ac33a4fe0bfeb802fc6b94611
- 출처 데이터셋
- uspto-grants-1994_12
- 특허 번호
- US05374606
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