Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
1-Benzyl-1H-benzotriazole → 1-(Phenylethynyl)naphthalene
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 1-Benzyl-1H-benzotriazole | HCID 521212 | — |
| 반응물 | N-(1-Naphthylmethylene)aniline | HCID 615538 | — |
| 용매 | Methanol | HCID 887 | — |
| 생성물 | 1-(Phenylethynyl)naphthalene | HCID 3108071 | 88% |
반응 단계
In a procedure similar to that of Example 16 using [phenylmethyl]-1H-benzotriazole (10 mmol) and N-([1-naphthalenyl]methylene)benzenamine (10 mmol): 88% yield: mp 51°-53° C. (MeOH) (lit1 oil); 1H NMR (300 MHz, CDCl3) δ7.39-7.69 (m, 8H), 7.77-7.90 (m, 3H), 8.46 (br d, 2.7H, 1H); IR (CDCl3) 3060 (s), 2245 (eyne), 1596, 1581, 1508, 1491 (s), 1442, 1398, 1333, 1215, 1070, 1017 cm1. MS (EI) m/e 228 (M+, 100).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05374701 |
| 출처 데이터셋 | uspto-grants-1994_12 |
| ORD ID | ord-bc05823c43bc402dbc26512c4892fff9 |
| 출처 메모 | uspto-grants-1994_12 |