Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Water → p-Octyloxybenzyl alcohol
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Water | HCID 962 | — |
| 반응물 | Sodium Fluoride | HCID 5235 | — |
| 반응물 | p-(Octyloxy)benzaldehyde | HCID 90358 | — |
| 반응물 | Aluminium lithium hydride | HCID 21226445 | — |
| 용매 | Tetrahydrofuran | HCID 8028 | — |
| 생성물 | p-Octyloxybenzyl alcohol | HCID 144261 | 99.5% |
반응 단계
To a suspension of lithium aluminum hydride (4.05 g) in tetrahydrofuran (475 ml) was added dropwise a solution of 4-octyloxybenzaldehyde (25 g) in tetrahydrofuran (25 ml) at 55°~60° C. The reaction mixture was stirred under reflux for 1 hour, and thereto was added sodium fluoride (35.84 g) and water (11.52 ml) under ice-cooling. The mixture was stirred for 30 minutes, and filtrated. The filtrate was evaporated in vacuo to give 4-octyloxybenzyl alcohol (25.1 g) as crystals.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05376634 |
| 출처 데이터셋 | uspto-grants-1994_12 |
| ORD ID | ord-ac6720baaa5b4e6185c20e134142525b |
| 출처 메모 | uspto-grants-1994_12 |