3-Pyridinecarboxaldehyde → HCID 9989787, 화합물

HRID 1493238노트

반응식

HRID 1493238 반응식
[CH:1]1[CH:6]=[N:5][CH:4]=[C:3]([CH:7]=O)[CH:2]=1.[CH3:9][N:10]([CH3:14])[CH2:11][CH2:12][NH2:13]>C1(C)C=CC=CC=1>[CH:7](=[N:13][CH2:12][CH2:11][N:10]([CH3:14])[CH3:9])[C:3]1[CH:2]=[CH:1][CH:6]=[N:5][CH:4]=1

참가 물질

4

반응물 2

HCID 103713-PyridinecarboxaldehydeHCID 66053N,N-Dimethylethylenediamine

생성물 1

HCID 9989787HCID 9989787, 화합물수율 102%

시약·촉매·용매 1

HCID 1140Toluene용매

실험 절차

Nicotinealdehyde (2.16 ml, 22.9 mmol) and N,N-dimethylethylenediamine (2.51 ml, 22.9 mmol) were added to toluene (100 ml) and the mixture was subjected to azeotropic dehydration for 2 hours. After cooling, solvent was distilled off to obtain N-nicotinylidene-N',N'-dimethylethylenediamine (4.13 g, yield 102%).

후처리

  1. temperatureAfter cooling
  2. distillationsolvent was distilled off

출처 및 근거

ORD 기록
ord-03ac82eee3b44876bb2f0cce64a26396
출처 데이터셋
uspto-grants-1991_06
특허 번호
US05021435

반응 노트

불러오는 중…