3-Bromodibenzo(b,d)thiophene → HCID 19887836, 화합물

반응식

Br[C:2]1[CH:3]=[CH:4][C:5]2[C:9]3[CH:10]=[CH:11][CH:12]=[CH:13][C:8]=3[S:7][C:6]=2[CH:14]=1.[CH3:15][Sn:16](C)([CH3:39])[C:17]1C=CC2C3C=CC(CO[Si](C(C)(C)C)(C)C)=CC=3OC=2C=1>>[CH3:15][Sn:16]([CH3:39])([CH3:17])[C:2]1[CH:3]=[CH:4][C:5]2[C:9]3[CH:10]=[CH:11][CH:12]=[CH:13][C:8]=3[S:7][C:6]=2[CH:14]=1

참가 물질

반응물 2

HCID 134156163-Bromodibenzo(b,d)thiophene

HCID 19437716HCID 19437716, 화합물

생성물 1

HCID 19887836HCID 19887836, 화합물수율 82%

실험 절차

Using the procedure described in Example 316, but substituting 3-bromodibenzothiophene for the bromodibenzofuran 10 of Example 316, provided the title compound in 82% yield.

출처 및 근거

ORD 기록: ord-53e1fd27b27a4f9ca92bc5efaa55bf7e
출처 데이터셋: uspto-grants-1991_06
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US05025008

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